Carotenoids obi
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☀ Pathway reconstructed carotenoids:       [  Search similar carotenogenesis pathway constructing organisms  ]  
  1. CA00001 (4,4'-Diapolycopene)
  2. CA00003 (Neo-4,4'-diaponeurosporene B)
  3. CA00004 (Neo-4,4'-diaponeurosporene C)
  4. CA00008 (4,4'-Diapophytoene)
  5. CA00007 (4,4'-Diapophytofluene)
  6. CA00005 (4,4'-Diapo-7,8,11,12-tetrahydrolycopene)
  7. CA00006 (4,4'-Diapo-ζ-carotene)
  8. CA00002 (4,4'-Diaponeurosporene)
  9. CA00023 (OH-Diaponeurosporene glucoside ester)
  10. CA00010 (4,4'-Diapolycopen-4-al)
  11. CA00011 (4,4'-Diaponeurosporen-4-al)
  12. CA01126 (Hydroxy-diaponeurosporenal)
  13. CA00034 (4,4'-Diapocaroten-4'-al-4-oic acid)
  14. CA00016 (4,4'-Diaplycopene-4,4'-dioic acid)
  15. CA00015 (4,4'-Diaponeurosporen-4-oic acid)
  16. CA00022 (β-D-glucosyl 4,4'-diaponeurosporenoic acid)
  17. CA00021 (Staphyloxanthin)
  18. CA00024 (Isostaphyloxanthin)
  19. CA00043 (Lycopene)
  20. CA00051 (ζ-Carotene)
  21. CA00042 (3,4-Dehydrolycopene)
☀ Pathway unconstructed carotenoids: CA00024 (Isostaphyloxanthin)
☀ Lycopene biosynthesis type: Bacterial type, Diapolycopene (Ref.690)

  ☀ CA00001 (4,4'-Diapolycopene) biosynthesis pathway

   Path: CA00008 (4,4'-Diapophytoene) -> CA00007 (4,4'-Diapophytofluene) -> CA00006 (4,4'-Diapo-ζ-carotene) -> CA00002 (4,4'-Diaponeurosporene) -> CA00001 (4,4'-Diapolycopene)

   See: CB000001 (Knwon path in bacterium: CA00008 -> CA00007 -> CA00006 -> CA00002 -> CA00001)

   Necessary enzymes for those reactions in theory: unknown (CR00272: CA00008 -> CA00007) --> unknown (CR00116: CA00007 -> CA00006) --> unknown (CR00133: CA00006 -> CA00002) --> CrtN(1.3.8.2) (CR00137: CA00002 -> CA00001)




  ☀ CA00003 (Neo-4,4'-diaponeurosporene B) biosynthesis pathway

   Path: CA00008 (4,4'-Diapophytoene) -> CA00007 (4,4'-Diapophytofluene) -> CA00006 (4,4'-Diapo-ζ-carotene) -> CA00002 (4,4'-Diaponeurosporene) -> CA00003 (Neo-4,4'-diaponeurosporene B)

   See: CB000001 (Knwon path in bacterium: CA00008 -> CA00007), CB000001 (Knwon path in bacterium: CA00007 -> CA00006), CB000001 (Knwon path in bacterium: CA00006 -> CA00002), Proposed reaction (CA00002 -> CA00003)

   Necessary enzymes for those reactions in theory: unknown (CR00272: CA00008 -> CA00007) --> unknown (CR00116: CA00007 -> CA00006) --> unknown (CR00133: CA00006 -> CA00002) --> unknown (CA00002 -> CA00003)




  ☀ CA00004 (Neo-4,4'-diaponeurosporene C) biosynthesis pathway

   Path: CA00008 (4,4'-Diapophytoene) -> CA00007 (4,4'-Diapophytofluene) -> CA00006 (4,4'-Diapo-ζ-carotene) -> CA00002 (4,4'-Diaponeurosporene) -> CA00004 (Neo-4,4'-diaponeurosporene C)

   See: CB000001 (Knwon path in bacterium: CA00008 -> CA00007), CB000001 (Knwon path in bacterium: CA00007 -> CA00006), CB000001 (Knwon path in bacterium: CA00006 -> CA00002), Proposed reaction (CA00002 -> CA00004)

   Necessary enzymes for those reactions in theory: unknown (CR00272: CA00008 -> CA00007) --> unknown (CR00116: CA00007 -> CA00006) --> unknown (CR00133: CA00006 -> CA00002) --> unknown (CA00002 -> CA00004)




  ☀ CA00005 (4,4'-Diapo-7,8,11,12-tetrahydrolycopene) biosynthesis pathway

   Path: CA00008 (4,4'-Diapophytoene) -> CA00007 (4,4'-Diapophytofluene) -> CA00005 (4,4'-Diapo-7,8,11,12-tetrahydrolycopene)

   See: CB000001 (Knwon path in bacterium: CA00008 -> CA00007), similar to CB000001: CA00006 -> CA00002 (proposed reaction: CA00007 -> CA00005)

   Necessary enzymes for those reactions in theory: unknown (CR00272: CA00008 -> CA00007) --> unknown (CA00007 -> CA00005)




  ☀ CA00023 (OH-Diaponeurosporene glucoside ester) biosynthesis pathway

   Path: CA00008 (4,4'-Diapophytoene) -> CA00007 (4,4'-Diapophytofluene) -> CA00006 (4,4'-Diapo-ζ-carotene) -> CA00002 (4,4'-Diaponeurosporene) -> CA00023 (OH-Diaponeurosporene glucoside ester)

   See: CB000001 (Knwon path in bacterium: CA00008 -> CA00007), CB000001 (Knwon path in bacterium: CA00007 -> CA00006), CB000001 (Knwon path in bacterium: CA00006 -> CA00002), Proposed reaction (CA00002 -> CA00023)

   Necessary enzymes for those reactions in theory: unknown (CR00272: CA00008 -> CA00007) --> unknown (CR00116: CA00007 -> CA00006) --> unknown (CR00133: CA00006 -> CA00002) --> unknown (CA00002 -> CA00023)




  ☀ CA00010 (4,4'-Diapolycopen-4-al) biosynthesis pathway

   Path: CA00008 (4,4'-Diapophytoene) -> CA00001 (4,4'-Diapolycopene) -> CA00010 (4,4'-Diapolycopen-4-al)

   See: CB000102 (Knwon path in Halobacillus: CA00008 -> CA00001), CR00005 (CA00001 -> CA00010)

   Necessary enzymes for those reactions in theory: CrtN (CR00013: CA00008 -> CA00001) --> CrtOx (CR00005: CA00001 -> CA00010)




  ☀ CA01126 (Hydroxy-diaponeurosporenal) biosynthesis pathway

   Path: CA00008 (4,4'-Diapophytoene) -> CA00002 (4,4'-Diaponeurosporene) -> CA00011 (4,4'-Diaponeurosporen-4-al) -> CA01126 (Hydroxy-diaponeurosporenal)

   See: CB000003 (Knwon path in Staphylococcus: CA00008 -> CA00002), CB000002 (Knwon path in bacterium: CA00002 -> CA00011), CR00211 (CA00011 -> CA01126)

   Necessary enzymes for those reactions in theory: CrtN(1.3.8.2) (CR00273: CA00008 -> CA00002) --> CrtN2 (CR00006: CA00002 -> CA00011) --> CrtOx (CR00211: CA00011 -> CA01126)




  ☀ CA00034 (4,4'-Diapocaroten-4'-al-4-oic acid) biosynthesis pathway

   Path: CA00008 (4,4'-Diapophytoene) -> CA00001 (4,4'-Diapolycopene) -> CA00010 (4,4'-Diapolycopen-4-al) -> CA00013 (4,4'-Diapolycopenedial) -> CA00034 (4,4'-Diapocaroten-4'-al-4-oic acid)

   See: CB000102 (Knwon path in Halobacillus: CA00008 -> CA00001), CR00005 (CA00001 -> CA00010), CR00008 (CA00010 -> CA00013), CR00222 (CA00013 -> CA00034)

   Necessary enzymes for those reactions in theory: CrtN (CR00013: CA00008 -> CA00001) --> CrtOx (CR00005: CA00001 -> CA00010) --> CrtOx (CR00008: CA00010 -> CA00013) --> CrtOx (CR00222: CA00013 -> CA00034)




  ☀ CA00016 (4,4'-Diaplycopene-4,4'-dioic acid) biosynthesis pathway

   Path: CA00008 (4,4'-Diapophytoene) -> CA00001 (4,4'-Diapolycopene) -> CA00010 (4,4'-Diapolycopen-4-al) -> CA00013 (4,4'-Diapolycopenedial) -> CA00016 (4,4'-Diaplycopene-4,4'-dioic acid)

   See: CB000102 (Knwon path in Halobacillus: CA00008 -> CA00001), CR00005 (CA00001 -> CA00010), CR00008 (CA00010 -> CA00013), CR00224 (CA00013 -> CA00016)

   Necessary enzymes for those reactions in theory: CrtN (CR00013: CA00008 -> CA00001) --> CrtOx (CR00005: CA00001 -> CA00010) --> CrtOx (CR00008: CA00010 -> CA00013) --> Ald (CR00224: CA00013 -> CA00016)




  ☀ CA00021 (Staphyloxanthin) biosynthesis pathway

   Path: CA00008 (4,4'-Diapophytoene) -> CA00002 (4,4'-Diaponeurosporene) -> CA00011 (4,4'-Diaponeurosporen-4-al) -> CA00015 (4,4'-Diaponeurosporen-4-oic acid) -> CA00022 (β-D-glucosyl 4,4'-diaponeurosporenoic acid) -> CA00021 (Staphyloxanthin)

   See: CB000003 (Knwon path in Staphylococcus: CA00008 -> CA00002 -> CA00011 -> CA00015 -> CA00022 -> CA00021)

   Necessary enzymes for those reactions in theory: CrtN(1.3.8.2) (CR00273: CA00008 -> CA00002) --> CrtN2 (CR00006: CA00002 -> CA00011) --> CrtOx (CR00221: CA00011 -> CA00015) --> NP_373087 (CR00307: CA00015 -> CA00022) --> NP_373089 (CR00289: CA00022 -> CA00021)




  ☀ CA00043 (Lycopene) biosynthesis pathway

   Path: CA00189 (Prephytoene pyrophosphate (diphosphate)) -> CA00060 (Phytoene) -> CA00058 ((all-E)-Phytofluene) -> CA00051 (ζ-Carotene) -> CA00047 (Neurosporene) -> CA00043 (Lycopene)

   See: CB000005 (Bacterial and fungal pathway: CA00189 -> CA00060 -> CA00058 -> CA00051 -> CA00047 -> CA00043)

   Necessary enzymes for those reactions in theory: CrtB(2.5.1.32), CitPsy(2.5.1.32), AtPSY(2.5.1.32) (CR00277: CA00189 -> CA00060) --> Crtlb(1.3.99.28), CrtI(1.3.99.28, 1.3.99.30, 1.3.99.31), Crtlb(1.3.99.28), PDS(1.3.99.29), Crtla(1.3.99.29) (CR00389: CA00060 -> CA00058) --> CrtI(1.3.99.28, 1.3.99.30, 1.3.99.31), Crtlb(1.3.99.28), PDS(1.3.5.5, 1.3.99.29), Crtla(1.3.99.29) (CR00115: CA00058 -> CA00051) --> PDS(1.3.5.5, 1.3.99.29), CitPDS1(1.3.5.5), BoPDS(1.3.5.5), CrtI(1.3.5.6, 1.3.99.28, 1.3.99.30, 1.3.99.31), Crtlb(1.3.99.28), CrtQa(1.3.5.6), CrtQb(1.3.5.6), ZDS(1.3.5.6) (CR00136: CA00051 -> CA00047) --> CrtI(1.3.5.6, 1.3.99.30, 1.3.99.31), CrtQa(1.3.5.6), CrtQb(1.3.5.6), ZDS(1.3.5.6), Crtlb(1.3.99.26) (CR00132: CA00047 -> CA00043)




  ☀ CA00042 (3,4-Dehydrolycopene) biosynthesis pathway

   Path: CA00060 (Phytoene) -> CA00058 ((all-E)-Phytofluene) -> CA00051 (ζ-Carotene) -> CA00047 (Neurosporene) -> CA00043 (Lycopene) -> CA00042 (3,4-Dehydrolycopene)

   See: CB000078 (Knwon path in mold: CA00060 -> CA00058 -> CA00051 -> CA00047 -> CA00043 -> CA00042)

   Necessary enzymes for those reactions in theory: Crtlb(1.3.99.28), CrtI(1.3.99.28, 1.3.99.30, 1.3.99.31), Crtlb(1.3.99.28), PDS(1.3.99.29), Crtla(1.3.99.29) (CR00389: CA00060 -> CA00058) --> CrtI(1.3.99.28, 1.3.99.30, 1.3.99.31), Crtlb(1.3.99.28), PDS(1.3.5.5, 1.3.99.29), Crtla(1.3.99.29) (CR00115: CA00058 -> CA00051) --> PDS(1.3.5.5, 1.3.99.29), CitPDS1(1.3.5.5), BoPDS(1.3.5.5), CrtI(1.3.5.6, 1.3.99.28, 1.3.99.30, 1.3.99.31), Crtlb(1.3.99.28), CrtQa(1.3.5.6), CrtQb(1.3.5.6), ZDS(1.3.5.6) (CR00136: CA00051 -> CA00047) --> CrtI(1.3.5.6, 1.3.99.30, 1.3.99.31), CrtQa(1.3.5.6), CrtQb(1.3.5.6), ZDS(1.3.5.6), Crtlb(1.3.99.26) (CR00132: CA00047 -> CA00043) --> CrtI (CR00119: CA00043 -> CA00042)



Ref.690 : Enfissi EM, Nogueira M, Bramley PM, Fraser PD, Plant J. 2017 Feb;89(4):774-788. doi: 10.1111/tpj.13428. Epub 2017 Feb 7., "The regulation of carotenoid formation in tomato fruit.", PMID: 27865019 DOI: 10.1111/tpj.13428
Since June 15th, 2015 by Junko Yabuzaki.